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Hey brothers, one of my clients imports silicon steel sheets and well ran into some trouble with the customs authorities over his latest shipment, to make a long story short the authorities claim he's imported plain carbon steel whereas he claims they're silicon steel sheets.

The authorities have furnished us with part of a metaluragy report after they analyzed the sheets so if any one out there deals in this stuff or knows about this stuff can you point me to a place I can read all about silicon steel sheets?

Thanks in advance.
 

Mitch

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Hey brothers, one of my clients imports silicon steel sheets and well ran into some trouble with the customs authorities over his latest shipment, to make a long story short the authorities claim he's imported plain carbon steel whereas he claims they're silicon steel sheets.

The authorities have furnished us with part of a metaluragy report after they analyzed the sheets so if any one out there deals in this stuff or knows about this stuff can you point me to a place I can read all about silicon steel sheets?

Thanks in advance.
You should be able to get everything you need from the maker of what you got. Below is the Wikipedia on it Silicon Steel. I can get you more research if you let me know what you need. I know you have limited access to the internet sites. I have a general knowledge about metals from my days as a gunsmith/machinist, but I'm not an expert.


Electrical steel
From Wikipedia, the free encyclopedia
(Redirected from Silicon steel)
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Electrical steel, also called lamination steel, silicon electrical steel, silicon steel or transformer steel, is specialty steel tailored to produce certain magnetic properties, such as a small hysteresis area (small energy dissipation per cycle, or low core loss) and high permeability.

The material is usually manufactured in the form of cold-rolled strips less than 2 mm thick. These strips are called laminations when stacked together to form a core. Once assembled, they form the laminated cores of transformers or the stator and rotor parts of electric motors. Laminations may be cut to their finished shape by a punch and die, or in smaller quantities may be cut by a laser.

Contents [hide]
1 Metallurgy
2 Grain orientation
3 Lamination coatings
4 Magnetic properties
5 Amorphous steel
6 Practical concerns
7 See also
8 References
9 External links



[edit] Metallurgy
Electrical steel is an iron alloy which may have from zero to 6.5% silicon (Si:5Fe). Silicon significantly increases the electrical resistivity of the steel, which decreases the induced eddy currents and thus reduces the core loss. Manganese and aluminum can be added up to 0.5%.

Increasing the amount of silicon inhibits eddy currents and narrows the hysteresis loop of the material, thus lowering the core losses. However, the grain structure hardens and embrittles the metal, which adversely affects the workability of the material, especially when rolling it. When alloying, the concentration levels of carbon, sulfur, oxygen and nitrogen must be kept low, as these elements indicate the presence of carbides, sulfides, oxides and nitrides. These compounds, even in particles as small as one micrometer in diameter, increase hysteresis losses while also decreasing magnetic permeability. The presence of carbon has a more detrimental effect than sulfur or oxygen. Carbon also causes magnetic aging when it slowly leaves the solid solution and precipitates as carbides, thus resulting in an increase in power loss over time. For these reasons, the carbon level is kept to 0.005% or lower. The carbon level can be reduced by annealing the steel in a decarburizing atmosphere, such as hydrogen.


[edit] Grain orientation
There are two main types of electrical steel: grain-oriented and non-oriented.

Grain-oriented electrical steel usually has a silicon level of 3% (Si:11Fe). It is processed in such a way that the optimum properties are developed in the rolling direction, due to a tight control (proposed by Norman P. Goss) of the crystal orientation relative to the sheet. Due to the special orientation, the magnetic flux density is increased by 30% in the coil rolling direction, although its magnetic saturation is decreased by 5%. It is used for the cores of high-efficiency transformers, electric motor and generators.

Non-oriented electrical steel usually has a silicon level of 2 to 3.5% and has similar magnetic properties in all directions, which makes it isotropic. It is less expensive and is used in applications where the direction of magnetic flux is changing, such as electric motors and generators. It is also used when efficiency is less important or when there is insufficient space to correctly orient components to take advantage of the anisotropic properties of grain-oriented electrical steel.


[edit] Lamination coatings
Electrical steel is usually coated to increase electrical resistance between laminations, to provide resistance to corrosion or rust, and to act as a lubricant during die cutting. There are various coatings, organic and inorganic, and the coating used depends on the application of the steel.[1] The type of coating selected depends on the heat treatment of the laminations, whether the finished lamination will be immersed in oil, and the working temperature of the finished apparatus. Former practice was to insulate each lamination with a layer of paper or a varnish coating, but this reduced the stacking factor of the core and limited the maximum temperature of the core. [2]


[edit] Magnetic properties
The magnetic properties of electrical steel are dependent on heat treatment, as increasing the average crystal size decreases the hysteresis loss. Hysteresis loss is determined by a standard test and for common grades of electrical steel may range from about 2 to 10 watts per kilogram (1 to 5 watts per pound) at 60 Hz and 1.5 tesla magnetic field strength. Semi-processed electrical steels are delivered in a state that, after punching the final shape, a final heat treatment develops the desired 150-micrometer grain size. The fully processed steels are usually delivered with insulating coating, full heat treatment, and defined magnetic properties, for applications where the punching operation does not significantly degrade the material properties. Excessive bending, incorrect heat treatment, or even rough handling of core steel can adversely effect its magnetic properties and may also increase noise due to magnetostriction [3]


[edit] Amorphous steel
For certain transformers, cores made of amorphous steel are used. This material is a metallic glass prepared by pouring molten alloy steel on a rotating cooled wheel, which cools the metal so quickly (a rate of about one million degrees per second) that crystals do not form. The resulting amorphous metal transformers may have losses due to the core material only one-third that of conventional steels. However, its high cost (about twice that of conventional steel) and lower mechanical properties make use of amorphous steel economical only for certain distribution-type transformers. [4]


[edit] Practical concerns
Core steel is much more costly than the mild steel used for apparatus tanks, generator frames, etc. - in 1981 it was more than twice the cost per unit weight. [5]

The size of magnetic domains in the sheet can be reduced by scribing the surface of the sheet with a laser, or mechanically. This greatly reduces the hysteresis losses in the assembled core. [6]
 
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Thank you for the info Mitch I'll look into it. Unfortunately I can't really get in touch with the manufacturer but my inquiry is more general in nature rather than what they supplied my client with. I need to know the chemical composition silicon steel sheets or a basic definition of what is considered as silicon steel sheets according to industrial standards.

At the present moment I do not have exact details of the case but if I'm able to come up with what the industrial standard for silicon steel is I can at least counter the report they're relying on to convict my client. From my basic research silicon steel consists of magnesium, phosphorus, silicon, sulphur and carbon.
 

Mitch

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Thank you for the info Mitch I'll look into it. Unfortunately I can't really get in touch with the manufacturer but my inquiry is more general in nature rather than what they supplied my client with. I need to know the chemical composition silicon steel sheets or a basic definition of what is considered as silicon steel sheets according to industrial standards.

At the present moment I do not have exact details of the case but if I'm able to come up with what the industrial standard for silicon steel is I can at least counter the report they're relying on to convict my client. From my basic research silicon steel consists of magnesium, phosphorus, silicon, sulphur and carbon.
Steel has numbers that signify what it is. Below is the break down of the steels in this class. If your spec sheets on it match up with this you should have no problem. If you don't understand any part of this PM me and I'll do my best to explain it, I understand the terms.


Silicon Steel (Electrical Steel)


When low carbon steel is alloyed with small quantities of silicon, the added volume resistivity helps to reduce eddy current losses in the core. Silicon
steels are probably of the most use to designers of motion control products
where the additional cost is justified by the increased performance. These
steels are available in an array of grades and thicknesses so that the material may be tailored for various applications. The added silicon has a marked impact on the life of stamping tooling, and the surface insulation selected also affects die life. Silicon steels are generally specified and selected on the basis of allowable core loss in watts/lb.

The grades are called out, in increasing order of core loss by M numbers,
such as M19, M27, M36 or M43, with each grade specifying a maximum core loss. (Note that this means that material can be substituted up , as M19 for M36, but not vice versa.) The higher M numbers (and thus higher core losses) are progressively lower cost, although only a few percent is saved with each step down in performance. M19 is probably the most common grade for motion control products, as it offers nearly the lowest core loss in this class of material, with only a small cost impact, particularly in low to medium production quantities.
In addition to grade, there are a number of other decisions to make regarding silicon steels. These are:

1. Semi vs. Fully processed material,
2. Annealing after stamping,
3. Material Thickness,
4. Surface insulation.

Fully processed material is simply material which has been annealed
to optimum properties at the steel mill. Semi processed material always
requires annealing after stamping in order to remove excess carbon as well as to stress relieve. The better grades of silicon steel are always supplied fully processed while semi processed is available only in grades M43 and worse. The designer considering semi processed M43 should evaluate Low Carbon Steel which may provide equivalent performance at lower cost.

Even though annealed at the mill, fully processed material may require further stress relief anneal after stamping. The stresses introduced during punching degrade the material properties around the edges of the lamination, and must be removed to obtain maximum performance. This is
particularly true for parts with narrow sections, or where very high flux
density is required. In one instance, a tachometer manufacturer was able to
reduce the stack height in his product by 10% by annealing after stamping. The annealing cycle requires a temperature of 1350-1450 F in a non oxidizing, non carburizing atmosphere. Endothermic, nitrogen, and vacuum atmospheres all work well. The selection of lamination thickness is a fairly
straightforward trade off of core loss versus cost. Thinner laminations exhibit lower losses (particularly as frequency increases), but thinner material is more expensive initially, and more laminations are required for a given stack height. The most common thicknesses are .014 in., .0185 in., and .025 in. (29 Gauge, 26 Gauge, and 24 Gauge, respectively.) These thicknesses are supplemented by thin electrical steels, available in .002, .004, and .007 in. thick. Thin electrical steels are available in one grade (Equivalent to M19) and are made by re-rolling standard silicon steel. Due to substantially higher material cost, thin electrical steel is used primarily for high performance and high frequency applications. In order to gain full advantage from a laminated core, the laminations must be insulated from one another. The simplest way to do this is to specify a surface insulation on the raw material. Silicon steels are available with several types of insulation:
--C-0:
Also called bare, or oxide coated. This is a thin, tightly adherent oxide
coating put on the material at the steel mill, or during the annealing process
after stamping. This is the lowest cost insulation, but offers little
resistance.
--C-3:
Enamel or varnish coating which offers excellent insulation, but parts so
coated cannot be annealed after stamping.
--C-4:An inorganic coating providing higher resistance than C-0, but which will withstand annealing temperatures.
--C-5:
An improved inorganic coating similar to C-4 but with significantly higher
resistance. It withstands annealing well in most cases. This is probably the
best choice for most performance sensitive applications. The main drawback to C-5 is an increase in tool wear due to abrasiveness.
 
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